Alex Bosworth written a great article about the Ajax Mistakes often made by the web developers. read here
And there is a wiki which says, what are the places to use Ajax.
If you are developing an application using Ajax, you may need one of these cool activity indicators to show the stuff from server is loading. Talking about that, we have a cool activity indicator 😉
Netjaxer helps you to have your web2.0 favorites on your desktop. Checkout their demo here
Here is a wonderful article talking about UI design for Ajax application
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